早拆模留设支撑情况下结构内力重分布研究

针对早拆模技术中,留设支撑后会改变结构内力分布,部分位置还会出现反向弯矩,内力重分布及产生的反向弯矩必然与原设计内力分布不同的问题,对受弯构件的内力弯矩的重新分布情况、产生反向弯矩情况进行了分析,以供早拆模施工分析结构承载能力作参考。     

水平或缓倾斜地层中房柱式采空区自稳性分析

指出采空区的稳定性评价问题是目前矿产开采及环境治理领域普遍关注的问题，在总结前人研究成果的基础上尝试利用应力扩散理论分析应力在水平或缓倾斜地层中房柱式采空区上浮岩土层内的传递规律及其上浮岩土层的移动变形过程，探讨了采空区的稳定性评价及其治理的新的分析方法。     

Thermal redistribution reactions of Blackglas™ ceramic

Several methods for the preparation of polyvinyl alcohol (PVA) hydrogel are being reported in the literature. In this communication a new, simple, and mild complexation reaction using phenyl boronic acid, leading to a highly elastic PVA hydrogel, is addressed. It is found that the inherent crystalline property of the semicrystalline PVA is retained by the complexation reaction, which is confined to the amorphous region. An enhanced mechanical property, particularly in the wet condition, is observed after the modification resulting from the intact crystallinity. Also, the inherent nontoxic characteristic property of PVA is unaffected upon this complexation reaction. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 143–149, 2001     

The role of technological availability for the distributive impacts of climate change mitigation policy

The impacts of the availability of low-carbon technologies on the regional distribution of mitigation costs are analyzed in a global multi-regional integrated assessment model. Three effects on regional consumption losses are distinguished: domestic measures, trade of fossil energy carriers and trade of emission permits. Key results are: (i) GDP losses and a redirection of investments in the energy system towards capital-intensive technologies are major contributions to regional consumption losses. (ii) A devaluation of tradable fossil energy endowments contributes largely to the mitigation costs of fossil fuel exporters. (iii) In case of reduced availability of low-carbon technologies, the permit market volume and associated monetary redistributions increase. The results suggest that the availability of a broad portfolio of low-carbon technologies could facilitate negotiations on the permit allocation scheme in a global cap-and-trade system.     

Efficient Algorithms for Block-Cyclic Redistribution of Arrays

The block-cyclic data distribution is commonly used to organize array elements over the processors of a coarse-grained distributed memory parallel computer. In many scientific applications, the data layout must be reorganized at run-time in order to enhance locality and reduce remote memory access overheads. In this paper we present a general framework for developing array redistribution algorithms. Using this framework, we have developed efficient algorithms that redistribute an array from one block-cyclic layout to another. Block-cyclic redistribution consists of index set computation , wherein the destination locations for individual data blocks are calculated, and data communication , wherein these blocks are exchanged between processors. The framework treats both these operations in a uniform and integrated way. We have developed efficient and distributed algorithms for index set computation that do not require any interprocessor communication. To perform data communication in a conflict-free manner, we have developed direct indirect and hybrid algorithms. In the direct algorithm, a data block is transferred directly to its destination processor. In an indirect algorithm, data blocks are moved from source to destination processors through intermediate relay processors. The hybrid algorithm is a combination of the direct and indirect algorithms. Our framework is based on a generalized circulant matrix formalism of the redistribution problem and a general purpose distributed memory model of the parallel machine. Our algorithms sustain excellent performance over a wide range of problem and machine parameters. We have implemented our algorithms using MPI, to allow for easy portability across different HPC platforms. Experimental results on the IBM SP-2 and the Cray T3D show superior performance over previous approaches. When the block size of the cyclic data layout changes by a factor of K , the redistribution can be performed in O( log K) communication steps. This is true even when K is a prime number. In contrast, previous approaches take O(K) communication steps for redistribution. Our framework can be used for developing scalable redistribution libraries, for efficiently implementing parallelizing compiler directives, and for developing parallel algorithms for various applications. Redistribution algorithms are especially useful in signal processing applications, where the data access patterns change significantly between computational phases. They are also necessary in linear algebra programs, to perform matrix transpose operations. Received June 1, 1997; revised March 10, 1998.     

Covalent dyads of porphyrin-fullerene and perylene-fullerene for organic photovoltaics: Spectroscopic and photocurrent studies

Supermolecular complexes of zinc porphyrin or perylenediimide as covalent dyads with fullerene (C₆₀) in chloroform and as Langmuir-Blodgett layers on an Au substrate were studied. In our studies we have used following spectroscopic methods: electronic absorption, fluorescence and electron spin resonance in solution. Also infrared absorption spectra in a KBr pellet and reflectance-absorption in Langmuir-Blodgett layers were monitored. Photocurrent generation in a photoelectrochemical cell was also studied. The redistribution of charge both upon porphyrin linkage to C₆₀ and when the systems are deposited on the Au substrate was shown. Photocurrent examinations show a great influence of the fullerene presence on photoresponse of the systems.     

“利益再分配”理念下的温州大南商圈提升规划策略

地处老城区的城市商圈因周边区域功能复杂、拓展空间有限,加之人流与交通繁杂,停车困难和购物环境缺乏吸引力等问题,导致商业竞争力日渐减弱。在此背景下,研究通过对温州大南商圈整治提升工程的研究,提出"利益再分配"的规划策略,并探讨这一策略对现今传统商圈改造提升的作用。     

硫酸盐侵蚀下轴心受压钢筋混凝土柱应力时变过程的数值分析

针对荷载和硫酸盐耦合作用过程中钢筋混凝土柱的应力分析问题,在已有混凝土内硫酸根离子扩散反应模型的基础上,进一步给出了硫酸盐侵蚀引起的混凝土损伤程度与硫酸根离子浓度及腐蚀时间之间的关系,建立了与损伤程度相关的混凝土腐蚀本构模型及轴压混凝土柱截面应力的计算方法,并通过数值模拟分析了柱截面内硫酸根离子传输、腐蚀损伤程度变化、截面应变和应力分布规律。结果表明:硫酸根离子浓度和混凝土损伤程度在柱截面内呈梯度分布,且受二维交互效应的影响明显;随腐蚀时间的增加,截面损伤区逐渐向内移动且其宽度增加,而混凝土应力在损伤区呈先增加后逐渐降低、在未损伤区基本呈线性增加的趋势。硫酸盐侵蚀过程中,轴压混凝土柱截面应力发生了明显的重分布现象。     

一种基于族相合性的文本增量聚类箅法

传统文本聚类方法只适合处理静态样本,且时间复杂度较高。针对该问题,提出一种基于簇相合性的文本增量聚类算法。采用基于词项语义相似度的文本表示模型,利用词项之间的语义信息,通过计算新增文本与已有簇之间的相合性实现对文本的增量聚类。增量处理完部分文本后,对其中错分可能性较大的文本重新指派类别,以进一步提高聚类性能。该算法可在对象数据不断增长或更新的情况下,避免大量重复计算,提高聚类性能。在20 Newsgroups数据集上进行实验,结果表明,与k-means算法和SHC算法相比,该算法可减少聚类时间,提高聚类性能。     

固载AlCl_3催化甲基三氯硅烷/三甲基氯硅烷再分配反应实验研究

针对有机硅单体二甲基二氯硅烷生产中的副产物—甲基三氯硅烷(—甲)和三甲基氯硅烷(三甲),采用固载 AlCl_3催化剂,在800mm×20mm(内径)的固定床反应器中进行一甲和三甲的再分配反应,制得二甲基二氯硅烷。通过催化剂筛选试验,结果表明以活性炭为载体的固载 AlCl_3催化剂为佳。通过工艺条件实验,确定了在活性炭固载 AlCl_3催化剂上一甲和三甲再分配反应的适宜工艺条件为:反应物摩尔比为1.0.液时空速 LHSV 为0.66 mL/(h·g-cat),反应温度为320℃,得到二甲收率70%左右。该催化剂还表现出一定的催化稳定性。